Synthesis of Molybdenum(VI) Neopentylidene Neopentylidyne Complexes
Mo(C-t-Bu)(CH-t-Bu)(Cl)(PMe₂Ph)₂ (1) was prepared as off-white crystals in 26% yield through addition of 2.5 equiv of Mg(CH₂-t-Bu)₂ to Mo(O)[OC(CF₃)₃]₄ in diethyl ether followed by 3 equiv of PMe₂Ph and a workup that includes dichloromethane (the source of Cl). Compound 1 is largely a syn isomer ini...
| Hoofdauteurs: | , , |
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| Formaat: | Artikel |
| Taal: | English |
| Gepubliceerd in: |
American Chemical Society (ACS)
2019
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| Online toegang: | https://hdl.handle.net/1721.1/122289 |