Identification of Reactive Intermediates Relevant to Dimethylgermylene Group Transfer Reactions of an Anthracene-Based Precursor

Dimethylgermylene ([Me₂Ge]) group transfer from the anthracene-based precursor dibenzo-7-dimethylgermanorbornadiene (Me₂GeA; A = C₁₄H₁₀, anthracene) was investigated. Transfer of [Me₂Ge] from Me₂GeA to 2,3-dimethylbutadiene to give a dihydrogermole (2) was mediated by a platinum metallagermacycle (1...

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Detalhes bibliográficos
Principais autores: Geeson, Michael Baily, Transue, Wesley, Cummins, Christopher C
Outros Autores: Massachusetts Institute of Technology. Department of Chemistry
Formato: Artigo
Idioma:English
Publicado em: American Chemical Society (ACS) 2019
Acesso em linha:https://hdl.handle.net/1721.1/122638