Intermolecular Reductive C–N Cross Coupling of Nitroarenes and Boronic Acids by P[superscript III]/P[superscript V]═O Catalysis

Intermolecular Reductive C–N Cross Coupling of Nitroarenes and Boronic Acids by P[superscript III]/P[superscript V]═O Catalysis

A main group-catalyzed method for the synthesis of aryl- and heteroarylamines by intermolecular C-N coupling is reported. The method employs a small-ring organophosphorus-based catalyst (1,2,2,3,4,4-hexamethylphosphetane) and a terminal hydrosilane reductant (phenylsilane) to drive reductive intermo...

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Bibliographic Details
Main Authors: Nykaza, Trevor Vincent, Cooper, Julian Colton, Li, Gen, Mahieu, Nolwenn, Ramirez, Antonio, Luzung, Michael R., Radosevich, Alexander T.
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:English
Published: American Chemical Society (ACS) 2020
Online Access:https://hdl.handle.net/1721.1/123674

Internet

https://hdl.handle.net/1721.1/123674

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