Driving Recursive Dehydration by PIII/PV Catalysis: Annulation of Amines and Carboxylic Acids by Sequential C–N and C–C Bond Formation
A method for the annulation of amines and carboxylic acids to form pharmaceutically relevant azaheterocycles via organophosphorus PIII/PV redox catalysis is reported. The method employs a phosphetane catalyst together with a mild bromenium oxidant and terminal hydrosilane reductant to drive successi...
Main Authors: | Lecomte, Morgan, Lipshultz, Jeffrey M., Kim-Lee, Shin-Ho, Li, Gen, Radosevich, Alexander T. |
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Other Authors: | Massachusetts Institute of Technology. Department of Chemistry |
Format: | Article |
Published: |
American Chemical Society (ACS)
2020
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Subjects: | |
Online Access: | https://hdl.handle.net/1721.1/124882 |
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