Diazomethane umpolung atop anthracene: An electrophilic methylene transfer reagent

Formal addition of diazomethane's terminal nitrogen atom to the 9,10-positions of anthracene yields H[subscript 2]CN[subscript 2]A (1, A = C[subscript 14]H[subscript 10] or anthracene). The synthesis of this hydrazone is reported from Carpino's hydrazine H[subscript 2]N[subscript 2]A throu...

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Bibliographic Details
Main Authors: Joost, Maximilian, Transue, Wesley J., Cummins, Christopher C.
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:English
Published: Royal Society of Chemistry (RSC) 2020
Online Access:https://hdl.handle.net/1721.1/124888