Diazomethane umpolung atop anthracene: An electrophilic methylene transfer reagent
Formal addition of diazomethane's terminal nitrogen atom to the 9,10-positions of anthracene yields H[subscript 2]CN[subscript 2]A (1, A = C[subscript 14]H[subscript 10] or anthracene). The synthesis of this hydrazone is reported from Carpino's hydrazine H[subscript 2]N[subscript 2]A throu...
Main Authors: | Joost, Maximilian, Transue, Wesley J., Cummins, Christopher C. |
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Other Authors: | Massachusetts Institute of Technology. Department of Chemistry |
Format: | Article |
Language: | English |
Published: |
Royal Society of Chemistry (RSC)
2020
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Online Access: | https://hdl.handle.net/1721.1/124888 |
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