Synthesis of Tungsten Oxo Alkylidene Biphenolate Complexes and Ring-Opening Metathesis Polymerization of Norbornenes and Norbornadienes
We have synthesized and characterized tungsten oxo alkylidene biphenolate complexes with the formulas W(O)(CHR)(rac-biphenolate)(PPhMe2) and (R,S)-[W(μ-O)(CHR)(biphenolate)]2 (R = CMe2Ph; biphenolate = L1 or L2 in the text). They behave as initiators for the stereoselective (cis,isotactic) polymeriz...
| Main Authors: | , , , |
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| Format: | Article |
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American Chemical Society (ACS)
2020
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| Online Access: | https://hdl.handle.net/1721.1/124980 |