Synthesis of acyl(chloro)phosphines enabled by phosphinidene transfer

Acyl(chloro)phosphines RC(O)P(Cl)(t-Bu) have been prepared by formal insertion of tert-butyl phosphinidene (t-Bu-P) from t-BuPA (A = C14H10 or anthracene) into the C-Cl bond of acyl chlorides. We show that the under-explored acyl(chloro)phosphine functional group provides an efficient method to prep...

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書目詳細資料
Main Authors: Szkop, Kevin M., Geeson, Michael B., Stephan, Douglas W., Cummins, Christopher C
其他作者: Massachusetts Institute of Technology. Department of Chemistry
格式: Article
語言:English
出版: Royal Society of Chemistry (RSC) 2020
在線閱讀:https://hdl.handle.net/1721.1/125274