Synthesis of acyl(chloro)phosphines enabled by phosphinidene transfer
Acyl(chloro)phosphines RC(O)P(Cl)(t-Bu) have been prepared by formal insertion of tert-butyl phosphinidene (t-Bu-P) from t-BuPA (A = C14H10 or anthracene) into the C-Cl bond of acyl chlorides. We show that the under-explored acyl(chloro)phosphine functional group provides an efficient method to prep...
| Main Authors: | , , , |
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| 其他作者: | |
| 格式: | Article |
| 語言: | English |
| 出版: |
Royal Society of Chemistry (RSC)
2020
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| 在線閱讀: | https://hdl.handle.net/1721.1/125274 |