Gas Phase Ethylene Polymerization by Single-Site Cr Centers in a MetalOrganic Framework

Gas Phase Ethylene Polymerization by Single-Site Cr Centers in a MetalOrganic Framework

We report a systematic study on the gas-phase polymerization of ethylene by a metal–organic framework (MOF) catalyst. Cr3+-exchanged MFU-4l (Cr(III)-MFU-4l, MFU-4l = Zn5Cl4(BTDD)3, H2BTDD = bis(1H-1,2,3,-triazolo[4,5-b],[4′,5′-i])dibenzo[1,4]dioxin)) serves as an exemplary system to demonstrate prer...

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Bibliographic Details
Main Authors: Park, Hoyoung Daniel, Comito, Robert J., Wu, Zhenwei, Zhang, Guanghui, Ricke, Nathan Darrell, Sun, Chenyue, Van Voorhis, Troy, Miller, Jeffrey T., Roman-Leshkov, Yuriy, Dinca, Mircea
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Published: 2020
Online Access:https://hdl.handle.net/1721.1/125651

Internet

https://hdl.handle.net/1721.1/125651

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