Direct Measurement of Radical-Catalyzed C₆H₆ Formation from Acetylene and Validation of Theoretical Rate Coefficients for C₂H₃+C₂H₂ and C₄H₅+C₂H₂ Reactions

Direct Measurement of Radical-Catalyzed C₆H₆ Formation from Acetylene and Validation of Theoretical Rate Coefficients for C₂H₃+C₂H₂ and C₄H₅+C₂H₂ Reactions

The addition of vinylic radicals to acetylene is an important step contributing to the formation of polycyclic aromatic hydrocarbons in combustion. The overall reaction 3C2H2 → C6H6 could result in large benzene yields, but without accurate rate parameters validated by experiment, the extent of arom...

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Bibliographic Details
Main Authors: Smith, Mica C., Liu, Guozhu, Buras, Zachary, Yang, Jeehyun, Green Jr, William H, Chu, Te-Chun, Ph. D. Massachusetts Institute of Technology.
Other Authors: Massachusetts Institute of Technology. Department of Chemical Engineering
Format: Article
Language:English
Published: American Chemical Society (ACS) 2020
Online Access:https://hdl.handle.net/1721.1/125689

Internet

https://hdl.handle.net/1721.1/125689

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