Bench-stable N -heterocyclic carbene nickel precatalysts for C−C and C−N bond-forming reactions

Bench-stable N -heterocyclic carbene nickel precatalysts for C−C and C−N bond-forming reactions

Herein, we introduce a new class of bench-stable N-heterocyclic carbene (NHC) nickel-precatalysts for homogeneous nickel-catalysis. The nickel(II) complexes are readily activated to Ni0 in situ under mild conditions, via a proposed Heck-type mechanism. The precatalysts are shown to facilitate carbon...

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Bibliographic Details
Main Authors: Strieth-Kalthoff, Felix, Longstreet, Ashley R., Weber, Jessica Marie, Jamison, Timothy F
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:English
Published: Wiley 2020
Online Access:https://hdl.handle.net/1721.1/125950

Internet

https://hdl.handle.net/1721.1/125950

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