Quo vadis niobium? Divergent coordination behavior of early-transition metals towards MOF-5

Quo vadis niobium? Divergent coordination behavior of early-transition metals towards MOF-5

Treatment of MOF-5 with NbCl[subscript 4](THF)[subscript 2] in acetonitrile leads to incorporation of Nb(iv) centers in a fashion that diverges from the established cation metathesis reactivity of this iconic material. A combination of X-ray absorption spectroscopy analysis and reactivity studies al...

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Bibliographic Details
Main Authors: Korzynski, Maciej Damian, Braglia, Luca, Borfecchia, Elisa, Lomachenko, Kirill A., Baldansuren, Amgalanbaatar, Hendon, Christopher H., Lamberti, Carlo, Dinca, Mircea
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:English
Published: Royal Society of Chemistry (RSC) 2020
Online Access:https://hdl.handle.net/1721.1/126242

Internet

https://hdl.handle.net/1721.1/126242

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