Surface Restructuring of Nickel Sulfide Generates Optimally Coordinated Active Sites for Oxygen Reduction Catalysis

The Ni₃S₂ bulk phase supports efficient oxygen reduction reaction (ORR) catalysis in pH neutral aqueous electrolytes. Here, we combine electrochemistry, surface spectroscopy, and high-resolution microscopy to show that Ni₃S₂ undergoes self-limiting oxidative surface restructuring under ORR conditio...

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Bibliographic Details
Main Authors: Yan, Bing, Krishnamurthy, Dilip, Hendon, Christopher H, Deshpande, Siddharth, Surendranath, Yogesh, Viswanathan, Venkatasubramanian
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:English
Published: Elsevier BV 2020
Online Access:https://hdl.handle.net/1721.1/126863