Electroactive Anion Receptor with High Affinity for Arsenate
Herein, we present the synthesis and characterization of a macrocyclic polyamide cage that incorporates redox-active 1,4-dithiin units. UV/vis titration experiments with eight anions in acetonitrile revealed high affinity for H2AsO4- (log β2 = 10.4-0.4+0.4) and HCO3- (log β2 = 8.3-0.4+0.3) over othe...
| Main Authors: | , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
American Chemical Society (ACS)
2020
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| Online Access: | https://hdl.handle.net/1721.1/128150 |