Selective Synthesis of Site-Differentiated Fe4S4 and Fe6S6 Clusters
Obtaining rational control over the structure and nuclearity of metalloclusters is an ongoing challenge in synthetic Fe-S cluster chemistry. We report a new family of tridentate imidazolin-2-imine ligands L(NIm R ) 3 that can bind [Fe 4 S 4 ] 2+ or [Fe 6 S 6 ] 3+ clusters, depending on the steric pr...
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| Format: | Article |
| Language: | English |
| Published: |
American Chemical Society (ACS)
2020
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| Online Access: | https://hdl.handle.net/1721.1/128194 |