Alternating current voltammetry of electrode reactions with constant surface activity: Application to electrolysis of molten electrolytes

Analytic solutions are derived for the alternating current voltammetry (ACV) harmonic waveforms of electrodeposition and gas evolution reactions where the surface activity of the reduced species R is constant. Reversible and quasi-reversible charge transfer kinetics are considered, as well as the ef...

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Bibliographic Details
Main Authors: Caldwell, Andrew Harvey, Allanore, Antoine
Other Authors: Massachusetts Institute of Technology. Department of Materials Science and Engineering
Format: Article
Language:English
Published: Elsevier BV 2021
Online Access:https://hdl.handle.net/1721.1/131072