Reversible Formation of Alkyl Radicals at [Fe<inf>4</inf>S<inf>4</inf>] Clusters and Its Implications for Selectivity in Radical SAM Enzymes
Copyright © 2020 American Chemical Society. All kingdoms of life use the transient 5′-deoxyadenosyl radical (5′-dAdoâ ) to initiate a wide range of difficult chemical reactions. Because of its high reactivity, the 5′-dAdo•must be generated in a controlled manner to abstract a specific H atom and avo...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
American Chemical Society (ACS)
2021
|
| Online Access: | https://hdl.handle.net/1721.1/132589 |