Why Conventional Design Rules for C–H Activation Fail for Open-Shell Transition-Metal Catalysts

© 2020 American Chemical Society. The design of selective and active C−H activation catalysts for direct methane-to-methanol conversion is challenging. Bioinspired complexes that form high-valent metal−oxo intermediates capable of hydrogen abstraction and rebound hydroxylation are promising candidat...

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Bibliographic Details
Main Authors: Nandy, Aditya, Kulik, Heather J
Other Authors: Massachusetts Institute of Technology. Department of Chemical Engineering
Format: Article
Language:English
Published: American Chemical Society (ACS) 2021
Online Access:https://hdl.handle.net/1721.1/134032