Continuum Theory of Electrostatic Correlations at Charged Surfaces

The standard model for diffuse charge phenomena in colloid science, electrokinetics, and biology is the Poisson-Boltzmann mean-field theory, which breaks down for multivalent ions and large surface charge densities because of electrostatic correlations. In this paper, we formulate a predictive conti...

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Bibliographic Details
Main Authors: de Souza, J Pedro, Bazant, Martin Z
Other Authors: Massachusetts Institute of Technology. Department of Chemical Engineering
Format: Article
Language:English
Published: American Chemical Society (ACS) 2021
Online Access:https://hdl.handle.net/1721.1/136117