Ionic activity in concentrated electrolytes: Solvent structure effect revisited

We revisit the role of the local solvent structure on the activity coefficients of electrolytes within a nonlocal dielectric function approach. We treat the concentrated electrolyte as a dielectric medium and suggest an interpolation formula for its nonlocal dielectric response. The water dielectric...

Full description

Bibliographic Details
Main Authors: Levy, Amir, Bazant, Martin, Kornyshev, Alexei
Format: Article
Language:English
Published: Elsevier BV 2021
Online Access:https://hdl.handle.net/1721.1/136630