Directed Palladium-Catalyzed Acetoxylation of Indolines. Total Synthesis of <i>N</i>-Benzoylcylindrocarine

We describe a palladium-catalyzed C7-acetoxylation of indolines with a range of amide directing groups. While a variety of substituents are tolerated on the indoline-core and the N1-acyl group, the acetoxylation is most sensitive to the C2- and C6-indoline substituents. The practicality of this indo...

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Bibliographic Details
Main Authors: Flynn, Kristen M, White, Kolby L, Movassaghi, Mohammad
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:English
Published: American Chemical Society (ACS) 2022
Online Access:https://hdl.handle.net/1721.1/141146