Postbiosynthetic modification of a precursor to the nitrogenase iron–molybdenum cofactor

© 2021 National Academy of Sciences. All rights reserved. Nitrogenases utilize Fe-S clusters to reduce N2to NH3. The large number of Fe sites in their catalytic cofactors has hampered spectroscopic investigations into their electronic structures, mechanisms, and biosyntheses. To facilitate their spe...

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Bibliographic Details
Main Authors: Srisantitham, Suppachai, Badding, Edward D, Suess, Daniel LM
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:English
Published: Proceedings of the National Academy of Sciences 2022
Online Access:https://hdl.handle.net/1721.1/141323