Expanding Deoxygenative Transformations of Alcohols by Phosphorus Compounds Through Geometric Deformation
Tricoordinate phosphorus (σ³-P) compounds act as strong O-atom acceptors in many deoxygenative transformations by forming strong P=O bonds in phosphine oxides. While typical trigonal σ³-P compounds are nucleophilic, it has been demonstrated that lowering the C₃ᵥ-symmetry of σ³-P compounds to Cₛ-symm...
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Massachusetts Institute of Technology
2022
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| Online Access: | https://hdl.handle.net/1721.1/143924 https://orcid.org/0000-0001-5526-4677 |