Investigations of Iron–Nitrogen Bonding at Synthetic Iron–Sulfur Clusters
The coordination chemistry of nitrogenous ligands at high-spin iron is investigated through the synthesis and characterization of a terminal imido complex of a cuboidal tetra(μ3-sulfido)tetrairon (Fe4S4) cluster. Structural, spectroscopic, and computational studies establish a dynamic interplay betw...
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Massachusetts Institute of Technology
2022
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| Online Access: | https://hdl.handle.net/1721.1/145013 https://orcid.org/0000-0001-9249-8894 |