Organometallic Chemistry in Fe–S Clusters
The organometallic chemistry of Fe–S clusters has emerged as a new area in Fe–S enzyme biochemistry. In particular, alkylated [Fe₄S₄] clusters are now thought to be important intermediates in several classes of enzymes, including radical S-adenosyl-L-methionine (SAM) enzymes and enzymes involved in...
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| Format: | Thesis |
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Massachusetts Institute of Technology
2022
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| Online Access: | https://hdl.handle.net/1721.1/145047 |