The Elusive Mononitrosylated [Fe 4 S 4 ] Cluster in Three Redox States
Iron-sulfur clusters are well-established targets in biological nitric oxide (NO) chemistry, but the key intermediate in these processes-a mononitrosylated [Fe4 S4 ] cluster-has not been fully characterized in a protein or a synthetic model thereof. Here, we report the synthesis of a three-member re...
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Format: | Article |
Language: | English |
Published: |
Wiley
2023
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Online Access: | https://hdl.handle.net/1721.1/148038 |