The Elusive Mononitrosylated [Fe 4 S 4 ] Cluster in Three Redox States

Iron-sulfur clusters are well-established targets in biological nitric oxide (NO) chemistry, but the key intermediate in these processes-a mononitrosylated [Fe4 S4 ] cluster-has not been fully characterized in a protein or a synthetic model thereof. Here, we report the synthesis of a three-member re...

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Bibliographic Details
Main Authors: Kim, Youngsuk, Sridharan, Arun, Suess, Daniel LM
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:English
Published: Wiley 2023
Online Access:https://hdl.handle.net/1721.1/148038