Synthesis of phosphiranes via organoiron-catalyzed phosphinidene transfer to electron-deficient olefins
Herein is reported the structural characterization and scalable preparation of the elusive iron–phosphido complex FpP(t Bu)(F) (2-F, Fp = (Fe(h5 -C5H5)(CO)2)) and its precursor FpP(t Bu)(Cl) (2-Cl) in 51% and 71% yields, respectively. These phosphide complexes are proposed to be relevant to an...
| Main Authors: | , , , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
Royal Society of Chemistry (RSC)
2023
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| Online Access: | https://hdl.handle.net/1721.1/148456 |