NMR detection and conformational dependence of two, three, and four-bond isotope shifts due to deuteration of backbone amides
Abstract NMR isotope shifts occur due to small differences in nuclear shielding when nearby atoms are different isotopes. For molecules dissolved in 1:1 H2O:D2O, the resulting mixture of N-H and N-D isotopes leads to a small splitting of resonances from adjacent nuclei. We used multid...
| Main Authors: | , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
Springer Netherlands
2023
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| Online Access: | https://hdl.handle.net/1721.1/150976 |