Experimental Characterization of Iron-Sulfur Cluster Excited States and their Relevance to Electron Transfer Reactions

Iron-sulfur (Fe−S) clusters, and cuboidal [Fe₄S₄] clusters in particular, are biologically ubiquitous metallocofactors involved in a diverse array of cellular processes. The electronic structures of these metallocofactors are highly multiconfigurational, and characterized by dense manifolds of low-e...

Full description

Bibliographic Details
Main Author: Skeel, Brighton A.
Other Authors: Suess, Daniel L.M.
Format: Thesis
Published: Massachusetts Institute of Technology 2024
Online Access:https://hdl.handle.net/1721.1/157058
https://orcid.org/0000-0001-8458-088X