Theory of Layered-Oxide Cathode Degradation in Li-ion Batteries by Oxidation-Induced Cation Disorder

Disorder-driven degradation phenomena, such as structural phase transformations and surface reconstructions, can significantly reduce the lifetime of Li-ion batteries, especially those with nickel-rich layered-oxide cathodes. We develop a general free energy model for layered-oxide ion-intercalation...

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Bibliographic Details
Main Authors: Zhuang, Debbie, Bazant, Martin Z
Other Authors: Massachusetts Institute of Technology. Department of Chemical Engineering
Format: Article
Language:English
Published: The Electrochemical Society 2024
Online Access:https://hdl.handle.net/1721.1/157531