Charge Storage Effect in a Trilayer Structure Comprising Germanium Nanocrystals

A metal-insulator-semiconductor (MIS) device with a trilayer insulator structure consisting of sputtered SiO₂ (~50nm)/evaporated pure germanium (Ge) layer (2.4nm)/rapid thermal oxide (~5nm) was fabricated on a p-type Si substrate. The MIS device was rapid thermal annealed at 1000°C. Capac...

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Main Authors: Heng, C.L., Choi, Wee Kiong, Chim, Wai Kin, Teo, L.W., Ho, Vincent, Tjiu, W.W., Antoniadis, Dimitri A.
Format: Article
Language:en_US
Published: 2003
Subjects:
Online Access:http://hdl.handle.net/1721.1/3969
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author Heng, C.L.
Choi, Wee Kiong
Chim, Wai Kin
Teo, L.W.
Ho, Vincent
Tjiu, W.W.
Antoniadis, Dimitri A.
author_facet Heng, C.L.
Choi, Wee Kiong
Chim, Wai Kin
Teo, L.W.
Ho, Vincent
Tjiu, W.W.
Antoniadis, Dimitri A.
author_sort Heng, C.L.
collection MIT
description A metal-insulator-semiconductor (MIS) device with a trilayer insulator structure consisting of sputtered SiO₂ (~50nm)/evaporated pure germanium (Ge) layer (2.4nm)/rapid thermal oxide (~5nm) was fabricated on a p-type Si substrate. The MIS device was rapid thermal annealed at 1000°C. Capacitance-voltage (C-V) measurements showed that, after rapid thermal annealing at 1000°C for 300s in Ar, the trilayer device exhibited charge storage property. The charge storage effect was not observed in a device with a bilayer structure without the Ge middle layer. With increasing rapid thermal annealing time from 0 to 400s, the width of the C-V hysteresis of the trilayer device increased significantly from 1.5V to ~11V, indicating that the charge storage capability was enhanced with increasing annealing time. High-resolution transmission electron microscopy results confirmed that with increasing annealing time, the 2.4nm amorphous middle Ge layer crystallized gradually. More Ge nanocrystals were formed and the crystallinity of the Ge layer improved as the annealing time was increased. When the measurement temperature was increased from –50°C to 150°C, the width of the hysteresis of the MIS device reduced from ~10V to ~6V. This means that the charge storage capability of the trilayer structure decreases with increasing measurement temperature. This is due to the fact that the leakage current in the trilayer structure increases with increasing measurement temperature.
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spelling mit-1721.1/39692019-04-10T18:40:00Z Charge Storage Effect in a Trilayer Structure Comprising Germanium Nanocrystals Heng, C.L. Choi, Wee Kiong Chim, Wai Kin Teo, L.W. Ho, Vincent Tjiu, W.W. Antoniadis, Dimitri A. metal-insulator-semiconductor devices sputtered SiO2 evaporated pure germanium charge storage effect trilayer structure A metal-insulator-semiconductor (MIS) device with a trilayer insulator structure consisting of sputtered SiO₂ (~50nm)/evaporated pure germanium (Ge) layer (2.4nm)/rapid thermal oxide (~5nm) was fabricated on a p-type Si substrate. The MIS device was rapid thermal annealed at 1000°C. Capacitance-voltage (C-V) measurements showed that, after rapid thermal annealing at 1000°C for 300s in Ar, the trilayer device exhibited charge storage property. The charge storage effect was not observed in a device with a bilayer structure without the Ge middle layer. With increasing rapid thermal annealing time from 0 to 400s, the width of the C-V hysteresis of the trilayer device increased significantly from 1.5V to ~11V, indicating that the charge storage capability was enhanced with increasing annealing time. High-resolution transmission electron microscopy results confirmed that with increasing annealing time, the 2.4nm amorphous middle Ge layer crystallized gradually. More Ge nanocrystals were formed and the crystallinity of the Ge layer improved as the annealing time was increased. When the measurement temperature was increased from –50°C to 150°C, the width of the hysteresis of the MIS device reduced from ~10V to ~6V. This means that the charge storage capability of the trilayer structure decreases with increasing measurement temperature. This is due to the fact that the leakage current in the trilayer structure increases with increasing measurement temperature. Singapore-MIT Alliance (SMA) 2003-12-20T19:03:35Z 2003-12-20T19:03:35Z 2002-01 Article http://hdl.handle.net/1721.1/3969 en_US Advanced Materials for Micro- and Nano-Systems (AMMNS); 354001 bytes application/pdf application/pdf
spellingShingle metal-insulator-semiconductor devices
sputtered SiO2
evaporated pure germanium
charge storage effect
trilayer structure
Heng, C.L.
Choi, Wee Kiong
Chim, Wai Kin
Teo, L.W.
Ho, Vincent
Tjiu, W.W.
Antoniadis, Dimitri A.
Charge Storage Effect in a Trilayer Structure Comprising Germanium Nanocrystals
title Charge Storage Effect in a Trilayer Structure Comprising Germanium Nanocrystals
title_full Charge Storage Effect in a Trilayer Structure Comprising Germanium Nanocrystals
title_fullStr Charge Storage Effect in a Trilayer Structure Comprising Germanium Nanocrystals
title_full_unstemmed Charge Storage Effect in a Trilayer Structure Comprising Germanium Nanocrystals
title_short Charge Storage Effect in a Trilayer Structure Comprising Germanium Nanocrystals
title_sort charge storage effect in a trilayer structure comprising germanium nanocrystals
topic metal-insulator-semiconductor devices
sputtered SiO2
evaporated pure germanium
charge storage effect
trilayer structure
url http://hdl.handle.net/1721.1/3969
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