PAG segregation during exposure affecting innate material roughness

We have developed an improved AFM-based technique to measure intrinsic material roughness (IMR) after base development. We have investigated the contribution of different polymeric PAGs to IMR. These polymeric PAGs include copolymers of several styrenic PAGs with hydroxystyrene. The IMR of these pol...

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Main Authors: Pottebaum, Indira, Cann, Susan G., Cabral, Alberto, Astolfi, David K., Fedynyshyn, Theodore H., Roberts, Jeanette M.
Other Authors: Lincoln Laboratory
Format: Article
Language:en_US
Published: The International Society for Optical Engineering 2010
Online Access:http://hdl.handle.net/1721.1/52663
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author Pottebaum, Indira
Cann, Susan G.
Cabral, Alberto
Astolfi, David K.
Fedynyshyn, Theodore H.
Roberts, Jeanette M.
author2 Lincoln Laboratory
author_facet Lincoln Laboratory
Pottebaum, Indira
Cann, Susan G.
Cabral, Alberto
Astolfi, David K.
Fedynyshyn, Theodore H.
Roberts, Jeanette M.
author_sort Pottebaum, Indira
collection MIT
description We have developed an improved AFM-based technique to measure intrinsic material roughness (IMR) after base development. We have investigated the contribution of different polymeric PAGs to IMR. These polymeric PAGs include copolymers of several styrenic PAGs with hydroxystyrene. The IMR of these polymer-bound PAGs is reduced relative to that of their nonpolymeric counterparts with DUV exposure. Theses results represent further evidence for PAG segregation during the bake steps as being responsible for increased IMR in exposed resists, presumably by increasing the dissolution rate inhomogeneity on a nano-scale level. The work also shows that the effects of PAG segregation can be mitigated by employing polymer-bound PAGs. 2
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spelling mit-1721.1/526632022-09-30T17:07:02Z PAG segregation during exposure affecting innate material roughness Pottebaum, Indira Cann, Susan G. Cabral, Alberto Astolfi, David K. Fedynyshyn, Theodore H. Roberts, Jeanette M. Lincoln Laboratory Fedynyshyn, Theodore H. Pottebaum, Indira Cann, Susan G. Cabral, Alberto Astolfi, David K. Fedynyshyn, Theodore H. We have developed an improved AFM-based technique to measure intrinsic material roughness (IMR) after base development. We have investigated the contribution of different polymeric PAGs to IMR. These polymeric PAGs include copolymers of several styrenic PAGs with hydroxystyrene. The IMR of these polymer-bound PAGs is reduced relative to that of their nonpolymeric counterparts with DUV exposure. Theses results represent further evidence for PAG segregation during the bake steps as being responsible for increased IMR in exposed resists, presumably by increasing the dissolution rate inhomogeneity on a nano-scale level. The work also shows that the effects of PAG segregation can be mitigated by employing polymer-bound PAGs. 2 Lincoln Laboratory Intel Corporation 2010-03-17T16:26:20Z 2010-03-17T16:26:20Z 2009-04 Article http://purl.org/eprint/type/JournalArticle 0277-786X http://hdl.handle.net/1721.1/52663 Fedynyshyn, Theodore H. et al. “PAG segregation during exposure affecting innate material roughness.” Advances in Resist Materials and Processing Technology XXVI. Ed. Clifford L. Henderson. San Jose, CA, USA: SPIE, 2009. 727349-11. © 2009 SPIE--The International Society for Optical Engineering en_US http://dx.doi.org/10.1117/12.814811 Proceedings of SPIE Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. application/pdf The International Society for Optical Engineering SPIE
spellingShingle Pottebaum, Indira
Cann, Susan G.
Cabral, Alberto
Astolfi, David K.
Fedynyshyn, Theodore H.
Roberts, Jeanette M.
PAG segregation during exposure affecting innate material roughness
title PAG segregation during exposure affecting innate material roughness
title_full PAG segregation during exposure affecting innate material roughness
title_fullStr PAG segregation during exposure affecting innate material roughness
title_full_unstemmed PAG segregation during exposure affecting innate material roughness
title_short PAG segregation during exposure affecting innate material roughness
title_sort pag segregation during exposure affecting innate material roughness
url http://hdl.handle.net/1721.1/52663
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