Two-Electron Reduction of a Vanadium(V) Nitride by CO to Release Cyanate and Open a Coordination Site
Generation of the nitrido functional group is commonly achieved by treatment of metal complexes with azide sources and is fostered by N2 extrusion.1 The analogous transformation involving isocyanate and production of CO is less well documented. A previous study by Fickes et al. showed that the...
| Main Authors: | , |
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| Format: | Article |
| Language: | en_US |
| Published: |
American Chemical Society
2011
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| Online Access: | http://hdl.handle.net/1721.1/64710 https://orcid.org/0000-0003-2568-3269 |