Tetraphosphabenzenes Obtained via a Triphosphacyclobutadiene Intermediate
An acyl triphosphirene ligand transfers an O atom to Nb to liberate the putative triphosphacyclobutadiene intermediate [RCP3{W(CO)5}2], which engages in [2+4]-cycloaddition reactions with an organic diene and a phosphaalkyne (see scheme; P orange, O red, W violet, C white). The latter reaction yield...
| Main Authors: | , |
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| Other Authors: | |
| Format: | Article |
| Language: | en_US |
| Published: |
WILEY-VCH
2011
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| Online Access: | http://hdl.handle.net/1721.1/64717 https://orcid.org/0000-0003-2568-3269 |