Nickel-Catalyzed Asymmetric Negishi Cross-Couplings of Racemic Secondary Allylic Chlorides with Alkylzincs
The transition metal-catalyzed enantioselective coupling of allylic electrophiles with carbon nucleophiles has been the focus of intense investigation.5 Salient examples include palladium-catalyzed couplings with enolates, nickel-catalyzed couplings with Grignard reagents, and copper-catalyzed coupl...
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Format: | Article |
Language: | en_US |
Published: |
Organic Syntheses, Inc.
2011
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Online Access: | http://hdl.handle.net/1721.1/67662 |