Oxidation Reactions Performed by Soluble Methane Monooxygenase Hydroxylase Intermediates H[subscript peroxo] and Q Proceed by Distinct Mechanisms
Soluble methane monooxygenase is a bacterial enzyme that converts methane to methanol at a carboxylate-bridged diiron center with exquisite control. Because the oxidizing power required for this transformation is demanding, it is not surprising that the enzyme is also capable of hydroxylating and ep...
| Main Authors: | , |
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| Other Authors: | |
| Format: | Article |
| Language: | en_US |
| Published: |
American Chemical Society
2011
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| Online Access: | http://hdl.handle.net/1721.1/67687 https://orcid.org/0000-0002-2693-4982 |