Tripodal Tris-tacn and Tris-DPA Platforms for Assembling Phosphate-Templated Trimetallic Centers

Multidentate tripodal ligands, N(CH2-m-C6H4-CH2tacn)3 (L1) and N(CH2-o-C6H4-CH2N(CH2py)2)3 (L2), have been devised for assembling high-nuclearity metal clusters. By using the same tripodal platform with different ligand appendages, either triazacyclononanes or dipicolylamines, and functionalizing ei...

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Bibliographic Details
Main Authors: Cao, Rui, Mueller, Peter, Lippard, Stephen J.
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society 2011
Online Access:http://hdl.handle.net/1721.1/67821
https://orcid.org/0000-0002-2693-4982