Simple Molybdenum(IV) Olefin Complexes of the Type Mo(NR)(X)(Y)(olefin)

Exposure of heptane solutions of Mo(NAr)(CHCMe2Ph)(Me2Pyr)(OAr) (1a; Ar = 2,6-diisopropylphenyl), Mo(NAr)(CHCMe3)(Me2Pyr)[OCMe(CF3)2] (1b), and Mo(NAr)(CHCMe2Ph)(Me2Pyr)(OSiPh3) (1c) to one atmosphere of ethylene for 12 h yields the ethylene complexes, Mo(NAr)(CH2CH2)(Me2Pyr)(OAr) (2a), Mo(NAr)(CH2C...

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Bibliographic Details
Main Authors: Marinescu, Smaranda C., King, Annie J., Schrock, Richard Royce, Singh, Rojendra, Muller, Peter, Takase, Michael K.
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society 2012
Online Access:http://hdl.handle.net/1721.1/69660
https://orcid.org/0000-0001-5827-3552