Insights into the different dioxygen activation pathways of methane and toluene monooxygenase hydroxylases

The methane and toluene monooxygenase hydroxylases (MMOH and TMOH, respectively) have almost identical active sites, yet the physical and chemical properties of their oxygenated intermediates, designated P*, H[subscript peroxo], Q, and Q* in MMOH and ToMOH[subscript peroxo] in a subclass of TMOH, To...

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Bibliographic Details
Main Authors: Bochevarov, Arteum D., Li, Jianing, Song, Woon Ju, Friesner, Richard A., Lippard, Stephen J.
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society (ACS) 2012
Online Access:http://hdl.handle.net/1721.1/71643
https://orcid.org/0000-0002-2693-4982