Probing substituent effects in aryl-aryl interactions using stereoselective diels-alder cycloadditions

Stereoselective Diels−Alder cycloadditions that probe substituent effects in aryl−aryl sandwich complexes were studied experimentally and theoretically. Computations on model systems demonstrate that the stereoselectivity in these reactions is mediated by differential π-stacking interactions in comp...

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Detalles Bibliográficos
Main Authors: Wheeler, Steven E., McNeil, Anne J., Muller, Peter, Swager, Timothy Manning, Houk, K. N.
Outros autores: Massachusetts Institute of Technology. Department of Chemistry
Formato: Artigo
Idioma:en_US
Publicado: American Chemical Society (ACS) 2012
Acceso en liña:http://hdl.handle.net/1721.1/72951