Reversible Dimerization of (+)-Myrmicarin 215B
Brønsted acid promoted reversible dimerization of myrmicarin 215B leads to formation of a new heptacyclic product, isomyrmicarin 430B, that possesses a C1,C2-trans,C2,C3-trans-substituted cyclopentane ring. Mechanistic studies illustrate that isomyrmicarin 430B arises by isomerization of isomyrmicar...
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Format: | Article |
Language: | en_US |
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American Chemical Society
2012
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Online Access: | http://hdl.handle.net/1721.1/73654 https://orcid.org/0000-0003-3080-1063 |