Reductive electrosynthesis of crystalline metal-organic frameworks
Electroreduction of oxoanions affords hydroxide equivalents that induce selective deposition of crystalline metal–organic frameworks (MOFs) on conductive surfaces. The method is illustrated by cathodic electrodeposition of Zn[subscript 4]O(BDC)[subscript 3] (MOF-5; BDC = 1,4-benzenedicarboxylate), w...
Main Authors: | , |
---|---|
Other Authors: | |
Format: | Article |
Language: | en_US |
Published: |
American Chemical Society (ACS)
2012
|
Online Access: | http://hdl.handle.net/1721.1/73975 https://orcid.org/0000-0002-1262-1264 https://orcid.org/0000-0002-4078-9435 |