Reductive electrosynthesis of crystalline metal-organic frameworks
Electroreduction of oxoanions affords hydroxide equivalents that induce selective deposition of crystalline metal–organic frameworks (MOFs) on conductive surfaces. The method is illustrated by cathodic electrodeposition of Zn[subscript 4]O(BDC)[subscript 3] (MOF-5; BDC = 1,4-benzenedicarboxylate), w...
Main Authors: | Li, Minyuan, Dinca, Mircea |
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Other Authors: | Massachusetts Institute of Technology. Department of Chemistry |
Format: | Article |
Language: | en_US |
Published: |
American Chemical Society (ACS)
2012
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Online Access: | http://hdl.handle.net/1721.1/73975 https://orcid.org/0000-0002-1262-1264 https://orcid.org/0000-0002-4078-9435 |
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