Toward Functional Carboxylate-Bridged Diiron Protein Mimics: Achieving Stability and Conformational Flexibility Using a Macrocylic Ligand

A dinucleating macrocycle, H[subscript 2]PIM, containing phenoxylimine metal-binding units has been prepared. Reaction of H[subscript 2]PIM with [Fe[subscript 2](Mes)[subscript 4]] (Mes = 2,4,6-trimethylphenyl) and sterically hindered carboxylic acids, Ph[subscript 3]CCO[subscript 2]H or ArTolCO[sub...

Full description

Bibliographic Details
Main Authors: Do, Loi Hung, Lippard, Stephen J.
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society (ACS) 2012
Online Access:http://hdl.handle.net/1721.1/74051
https://orcid.org/0000-0002-2693-4982