Claisen Rearrangement of Graphite Oxide: A Route to Covalently Functionalized Graphenes

On the GO: The basal plane allylic alcohol functionality of graphite oxide (GO) can be converted into N,N-dimethylamide groups through an Eschenmoser–Claisen sigmatropic rearrangement by using N,N-dimethylacetamide dimethyl acetal. Subsequent saponification of these groups affords the carboxylic aci...

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Bibliographic Details
Main Authors: Collins, William R., Lewandowski, Wiktor, Schmois, Ezequiel, Walish, Joseph John, Swager, Timothy M
Other Authors: Massachusetts Institute of Technology. Institute for Soldier Nanotechnologies
Format: Article
Language:en_US
Published: Wiley Blackwell 2012
Online Access:http://hdl.handle.net/1721.1/74222
https://orcid.org/0000-0002-3503-2120