Dynamic nuclear polarization with a rigid biradical

Dynamic nuclear polarization with a rigid biradical

A new polarizing agent with superior performance in dynamic nuclear polarization experiments is introduced, and utilizes two TEMPO (2,2,6,6-tetramethylpiperidine-1-oxyl) moieties connected through a rigid spiro tether (see structure). The observed NMR signal intensities were enhanced by a factor of...

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Bibliographic Details
Main Authors: Matsuki, Yoh, Maly, Thorsten, Ouari, Olivier, Karoui, Hakim, Le Moigne, Francois, Rizzato, Egon, Lyubenova, Sevdalina, Herzfeld, Judith, Prisner, Thomas, Tordo, Paul, Griffin, Robert Guy
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: John Wiley & Sons, Inc. 2012
Online Access:http://hdl.handle.net/1721.1/74234
https://orcid.org/0000-0003-1589-832X

Internet

http://hdl.handle.net/1721.1/74234
https://orcid.org/0000-0003-1589-832X

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