“Click” Synthesis of Heteroleptic Tris-cyclometalated Iridium(III) Complexes: Cu(I) Triazolide Intermediates as Transmetalating
Efficient synthesis of heteroleptic tris-cyclometalated Ir(III) complexes mer-Ir(C/\N)[subscript 2](trpy) (trpy = 2-(1H-[1,2,3]triazol-4-yl)pyridine) is achieved by using the Cu(I)-triazolide intermediates formed in “click” reactions as transmetalating reagents. Ligand preparation and cyclometalatio...
| Main Authors: | , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | en_US |
| Published: |
American Chemical Society (ACS)
2012
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| Online Access: | http://hdl.handle.net/1721.1/74567 |