Suppression of Phase Separation in LiFePO 4 Nanoparticles During Battery Discharge
Using a novel electrochemical phase-field model, we question the common belief that LiXFePO₄ nanoparticles always separate into Li-rich and Li-poor phases during battery discharge. For small currents, spinodal decomposition or nucleation leads to moving phase boundaries. Above a critical current den...
| Main Authors: | , |
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| Other Authors: | |
| Format: | Article |
| Language: | en_US |
| Published: |
American Chemical Society
2013
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| Online Access: | http://hdl.handle.net/1721.1/77987 |