Rigid Orthogonal Bis-TEMPO Biradicals with Improved Solubility for Dynamic Nuclear Polarization

Rigid Orthogonal Bis-TEMPO Biradicals with Improved Solubility for Dynamic Nuclear Polarization

The synthesis and characterization of oxidized bis-thioketal-trispiro dinitroxide biradicals that orient the nitroxides in a rigid, approximately orthogonal geometry are reported. The biradicals show better performance as polarizing agents in dynamic nuclear polarization (DNP) NMR experiments as com...

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Bibliographic Details
Main Authors: Dane, Eric L., Corzilius, Bjorn, Rizzato, Egon, Stocker, Pierre, Maly, Thorsten, Smith, Albert A., Griffin, Robert Guy, Ouari, Olivier, Tordo, Paul, Swager, Timothy M
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society 2013
Online Access:http://hdl.handle.net/1721.1/78309
https://orcid.org/0000-0003-1589-832X

Internet

http://hdl.handle.net/1721.1/78309
https://orcid.org/0000-0003-1589-832X

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