Thiophene-based covalent organic frameworks

We report the synthesis and characterization of covalent organic frameworks (COFs) incorporating thiophene-based building blocks. We show that these are amenable to reticular synthesis, and that bent ditopic monomers, such as 2,5-thiophenediboronic acid, are defect-prone building blocks that are sus...

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Bibliographic Details
Main Authors: Bertrand, Guillaume, Michaelis, Vladimir K., Ong, Ta-Chung, Griffin, Robert Guy, Dinca, Mircea
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: National Academy of Sciences (U.S.) 2013
Online Access:http://hdl.handle.net/1721.1/81293
https://orcid.org/0000-0003-1589-832X
https://orcid.org/0000-0002-1262-1264
https://orcid.org/0000-0002-6708-7660